BPED | Bipolar Electrodialysis

Operating Principle

BPED is an ion-exchange membrane process that uses bipolar and ion-exchange membranes to convert salts into acids and bases.

A bipolar membrane combines a cation-exchange layer (CEL) and an anion-exchange layer (AEL). An applied electric field dissociates water (H₂O) into hydrogen ions (H⁺) and hydroxide ions (OH⁻) at the interface.
The H⁺ and OH⁻ combine with anions and cations transferred from the feed salt to form acids and bases. The generalized reaction is MX + H₂O → HX + MOH (M⁺: cation, X⁻: anion).

For example, sodium sulfate (Na₂SO₄) can be converted into sulfuric acid (H₂SO₄) and sodium hydroxide (NaOH), depending on process configuration and operating conditions.

BPED therefore transforms waste salts into reusable acid and base resources.

BPED acid and base conversion principle
BPED acid and base conversion principle

BPED Advantages

Converting Salts into Acids and Bases

Converts waste and by-product salts into acids and bases for reuse in the process.

Reduced External Chemical Consumption

Water dissociation in bipolar membranes can reduce the amount of externally supplied acid and alkali required by a process.

Waste Salt Recovery

Recovers useful chemical feedstocks from inorganic or by-product salts that would otherwise be discarded.

Simultaneous Separation and Conversion

Ion separation, migration, and acid and base production take place within one ion-exchange membrane system.

Process Integration

The acids and bases produced can be reused in pretreatment, pH control, cleaning and manufacturing through closed-loop process configurations.

Applications

Waste Salt & High-Salinity Wastewater Recovery

  • Conversion of Na₂SO₄, NaCl and other waste salts into acids and bases
  • Resource recovery from high-salinity industrial wastewater
  • Recovery and reuse of inorganic salts in wastewater

Battery, Metal & Chemical Industries

  • Treatment of by-product salts from battery materials manufacturing
  • Metal refining and hydrometallurgical processes
  • Plating and surface-treatment processes
  • Treatment of waste brines from chemical processes

Acid & Base Recovery and Regeneration

  • Production and reuse of acid and alkali process chemicals
  • Production of chemicals for in-process pH control
  • Recovery of organic acids from organic acid salts
  • Regeneration and circulation of process chemicals

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