ED | Electrodialysis

Operating Principle

ED is an ion-exchange membrane process that uses a DC electric field to selectively separate and concentrate ions in aqueous solutions.

Cation-exchange membranes (CEMs) and anion-exchange membranes (AEMs) are arranged alternately. Under an applied electric field, cations move toward the cathode (−) and anions toward the anode (+).

Cations selectively pass through CEMs and are restricted by AEMs, while anions pass through AEMs and are restricted by CEMs.
This selective ion migration creates diluate chambers with reduced ion concentrations and concentrate chambers where ions accumulate.

The process enables simultaneous desalination and concentration. Depending on operating conditions and membrane characteristics, selective separation and recovery of specific ions are also possible.

ED ion-exchange membrane separation principle
ED ion-exchange membrane separation principle

ED Advantages

Simultaneous Desalination and Concentration

Produces diluate and concentrate streams in a single process.

Reduced Chemical Dependence

Ion migration does not require separate acid or alkali regeneration, helping reduce chemical consumption.

Selective Ion Separation

Ion-exchange membrane properties enable selective transfer of ionic substances. Selective membranes can enhance separation of specific groups of ions.

Suitable for High-Salinity Streams

An electric field rather than a pressure difference drives the process, allowing flexible application to industrial wastewater and concentrated brines.

Precise Operating Control

Voltage, current density, flow and the number of stages can be adjusted to control treated water quality and concentration.

Applications

Desalination & Water Treatment

  • Desalination of industrial process and reuse water
  • Desalination of saline and brackish water
  • Reuse of cooling water and cooling-tower blowdown
  • Removal of dissolved salts from industrial wastewater
  • Desalination of food and chemical process solutions

Concentration & Resource Recovery

  • Concentration of inorganic and process salts
  • Recovery of metals and valuable ions
  • Concentration of high-salinity wastewater
  • Pre-concentration before evaporation and crystallization
  • Recovery and reuse of wastewater salts

Selective Ion Separation

  • Separation of monovalent and multivalent ions
  • Separation of specific cations or anions
  • Removal of unwanted ions from process solutions
  • Purification of high-purity salts and chemical feedstocks

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